In this paper, MIL-53(Al) was synthesized by solvothermal method and its application as an adsorbent to remove rhodamine B from aqueous solution. The material was characterized using X-ray diffraction, Fourier-transform infrared spectroscopy, nitrogen adsorption-desorption isotherms, and scanning electron microscopy. The results show that the material has a large specific surface area (1028.3 m2/g). The rhodamine B adsorption on MIL-53(Al) occurs very quickly in the first minutes of contact. Two pseudo-first order and pseudo-second order adsorption kinetic models, and two adsorption isotherm models, including Langmuir and Freundlich, were used to analyze the adsorption data.

Investigating the characteristics of the three-step sorption of Sc on armchair silicene nanoribbons is the aim of this study. Since absorbed energy is the largest of the bridge, hollow, valley, and top positions, the hollow position is selected first. The structural state of the second step has an energy of adsorption of 4.18 Å and a bond length of 2.36 Å for Si-Si. Finally, ASiNRs with a high Sc atom had their 1.25 Å surface modified. Adsorbed ASiNRs resulted in new materials with semi-metal and magnetic characteristics, suggesting potential use in spintronic and electronic devices in the future.

In the paper, we investigate the structure and electronic properties of the pristine germanene nanoribbon and four adsorption configurations of 1F and 2F on the substrate of germanene nanoribbon. We obtained the parameters of the most stable structures of pristine germanene nanoribbon and four adsorption configurations. The band structure and the density of state and the part density of state for each element were also obtained. Findings show the adsorption configuration of 1F-GeNR.bridge has no band structure, while other configurations are semimetals with band gap from 0.175eV to 0.67eV; both four adsorption configurations are chemisorption and non-magnetic. The charge distribution of all configurations also was investigated; it showed that there is a charge shift from Ge atoms towards F atoms due to their electronegativity difference.

Applying first-principles calculations, the investigation of the geometrical and electronic properties of Pr adsorption armchair silicene nanoribbons structure has been established. The results show that the bandgap doped Pr has been changed, which is the case for chemical adsorption on the surface of ASiNRs; this material became metallic with the peak of valance band contact fermi level. Moreover, the survey to find the optimal height 1.82 Å of Pr and 2.24 Å bond length Si-Si, and Si-Si-Si bond angle 108005’, energy adsorption is -7.65 eV, buckling is 0.43 Å with structure stability close to the pristine case, has brought good results for actively creating newly applied materials for the spintronic and optoelectronics field in the future.

Heavy metal pollution is a major problems in the environment. The impact of toxic metal ions can be minimized by different technologies, viz., chemical precipitation, membrane filtration, oxidation, reverse osmosis, flotation and adsorption. But among them, adsorption was found to be very efficient and common due to the low concentration of metal uptake and economically feasible properties. In this review paper, Fe–Mn binary oxide incorporated into diatomite (Fe/Mn-diatomite) was prepared by a simple coating method , and removal of Cu(II) from aqueous solutions. The effects of three independent variables including initial ion concentration, removal time, and adsorbent dosage were investigated on the maximum adsorption of Cu (II). The optimum conditions for the adsorption of Cu(II) was obtained: 75 ppm of initial ion concentration, 150 min of removal time and 1.5 g/l of adsorbent. The maximum removal efficiencies of Cu(II) was obtained 86.25%. The results showed that Fe/Mn-diatomite was apable of treating copper metal in wastewater.

Environmental issues such as the wastewater have influenced each aspect of our lives. For human and environmental health protection, it is necessary to remove excess zinc in industrial wastewaters before discharging them to environment. Modified diatomite displayed larger surface area and pore volumes in comparison with untreated natural diatomite, which favored heavy metals sorption behavior. In this study, the removal of Zn(II) ions from aqueous solution was studied using Fe/Mn modified diatomite sample at different adsorption parameters such as contact initial metal ions concentration, dosage of Fe/Mn-Diatomite and ionic strength Na2CO3 on ionic Zn2+ adsorption capacity of diatomite modified. The residual zinc concentration in the solution was determined using flame atomic absorption spectroscopy. The results showed that: the gravitational increase increases with increasing time and then becomes almost stable, with 120 minutes timeliness; absorption increases when Fe/Mn-Ditomite is increased, absorption reaches 89.48% at a dose of 1.5 g/l; additional different concentrations Na2CO3 ranged from 0 ppm to 80 ppm the results showed that performance treatment Zn2+ of correspond 94,85%. This study could lay an essential foundation to develop modified diatomite for heavy metal removal from wastewater.

The study aims to investigate the possibility of processing copper metal (Cu2+) with activated carbon prepared from macadamia shell. Activated carbon is prepared from Macadamia shell by chemical agent H3PO4 with coke ratio: H3PO4 = 1:1, optimal temperature condition is 5000C and burning time is 60 minutes. Using the assumed Cu2+ metal treats materials in the laboratory with a concentration of 30ppm. The research to result ability material adsorbed Cu2+ metal achieve good performance 95.92% handle, corresponding to the concentration of Cu2+ reduced from 30 mg/l to 1.2mg/l in optimal conditions is pH = 4.5 , dosage 1.8g/l, time 30 minutes. The results showed that activated carbon prepared from macadamia husk with chemical agent H3PO4 was capable of treating copper metal in wastewater.

Investigation of the possibility of treating wastewater containing Cu2+ heavy metal with activated carbon material prepared from macadamia husk with activating K2CO3 in Optimal conditions such as temperature 6500C and burning time is 60 minutes. Survey results show that coal with the ability to handle heavy metals is best at 84.02% in optimal conditions such as pH=5 and time. Baking is 30 minutes. The results show similarities with other research results and are applicable to wastewater treatment Cu2+.

Using modified macadamia carbon by H2O2 as adsorbent to remove Zn2+ with H2O2 25% in 48 hours. The Parameters, such as pH, dosage and adsorption time affect the processing ability of modified macadamia carbon H2O2. The maximum removal efficiency of 64.52% was obtained at a pH of 4.5, the processing time is 80 minutes, dosage 1.8 g/L and an initial heavy metal concentration of 25ppm.

Macadamia shells were used to prepare modified carbon by chemical agent H2O2 (25%) in 48 hours with coke ratio: H2O2 = 1:10. Modified carbon from Macadamia shells with chemical agent H2O2 has capable of adsorption heavy metal copper (Cu 2+ ) at an assumption concentration is 30ppm in the optimum conditions such as pH = 4, dose is 1.8 g/l, and the processing time is 30 minutes. The result showed that the adsorption ability of the material reached the highest efficiency is 78.33%. This result showed that modified carbon from shells Macadamia by chemical agent H2O2 capable of removing applications on heavy metal copper (Cu2+) in wastewater.

Survey of methylene orange wastewater treatment by activated carbon material prepared from macadamia husk with chemical activator H3PO4 shows that coal with the best methylene orange color treatment is achieved Optimal conditions such as pH = 5, coal dose 0.9 g/L and time 120 minutes. The results show that it is applicable to color wastewater treatment and the results are similar to other research results.

Investigate the possibility of treating wastewater containing heavy metals Zn2+ with activated carbon material prepared from macadamia shell with chemical activating agent H3PO4, showing high efficiency of adsorption of Zn2+. The results of the study showed that activated carbon with H3PO4 activating agent has high adsorption capacity, capable of handling Zn2+ best at pH = 4.5, dosage 1.8 g/L and time is 120 minutes. . The results show similarities with other research results and are capable of treating wastewater containing heavy metals Zn2+.