Advanced materials have been of interest in recent years because of their outstanding properties that bring many useful applications to humans, they can be highly compatible with alternative materials. In particular, coating materials on HAp base increase the biocompatibility of HAp. In this study, we synthesize TiO2/HAp composite materials using the sol - gel method. Samples were made under different synthesis conditions in terms of HAp/TTIP ratios: (1:1); (1:1.5); (1:2); (1:2.5); (1:3). Factors affecting the synthesis process, such as the incubation time and pH of the solution, were also investigated. The optimal conditions for the synthesis process are the ratio HAp/TTIP: 1 gram HAp with 2 ml TTIP; stirring time: 16 hours; pH of the gel solution: pH = 0.5, as determined from the analysis of the X-ray diffraction spectrum and SEM surface morphology. The research results are the basis for research on biomedical materials.